Reaction of 2,5-(Dibenzothiazolin-2-yl)thiophene with Some Metal Ions |
| |
| Authors: | A.S. Salameh H.A. Tayim |
| |
| Affiliation: | Department of Chemistry, American University of Beirut Beirut, Lebanon |
| |
| Abstract: | 2,5-(Dibenzothiazolin-2-yl)thiophene has been synthesized by the reaction of 2,5-thiophenedicarboxaldehyde and -aminobenzenethiol. It reacts as a neutral ligand with Pd(II). However, it reacts as a dianion with Cu(II), Ag(I), Cd(II), Pb(II) and Zn(II), suggesting that the ligand is bonded as the conjugate base of the Schiff base 2,5-thiophenediylbis{N-(pheylen-2-thiol)aldimine}. Its behavior with Hg(II), Ru(III), Pt(II), Rh(III) and Ni(II) involves the opening of one of the thiazoline rings of the ligand. |
| |
| Keywords: | Author to whom correspondence should be addressed present address: Department of Chemistry, University of Petroleum & Minerals, Dhahran, Saudi Arabia. |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
