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Non-newtonian behavior of associations of macromolecules in dilute solutions
Authors:Claude Wolff
Affiliation:Laboratoire de Mécanique et Rheólogie, Ecole Nationale Supérieure des Industries Textiles, 11 rue Alfred Werner, F-68093 Mulhouse, Cedex, France
Abstract:The shear-thickening of dilute of flexble macromolecules of high molecular weight is explained theoretically assuming the existance of one-to-one reversible, concentration and shear rate dependent association between the macromolecules. The theoretical curves obtained are in fairly good agreement with the experimental results.
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