Non-newtonian behavior of associations of macromolecules in dilute solutions |
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Authors: | Claude Wolff |
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Affiliation: | Laboratoire de Mécanique et Rheólogie, Ecole Nationale Supérieure des Industries Textiles, 11 rue Alfred Werner, F-68093 Mulhouse, Cedex, France |
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Abstract: | The shear-thickening of dilute of flexble macromolecules of high molecular weight is explained theoretically assuming the existance of one-to-one reversible, concentration and shear rate dependent association between the macromolecules. The theoretical curves obtained are in fairly good agreement with the experimental results. |
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