Water addition to a two-electron mixed-valence bimetallic center |
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| Authors: | Veige Adam S Nocera Daniel G |
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| Institution: | Department of Chemistry, 6-335, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, MA 02139-4307, USA. |
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| Abstract: | Water adds to the two-electron mixed-valence Ir(0,II)(2) core of Ir(2)(tfepma)(3)Cl(2)(tfepma = MeNP(OCH(2)CF(3))(2)](2)) to cleanly generate an Ir(I,III)(2) hydride. Dehydrohalogenation across the Ir-Ir bond returns the complex to an Ir(0,II)(2) species. |
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