Synthesis and crystal structure of cyanohydrin trimethylsilyl ether of o-chlorobenzoylferrocene |
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| Authors: | Hai-Ying Zhao Zhan-Xi Bian Bao-Guo Li |
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| Institution: | (1) College of Chemistry and Chemical Engineering, Inner Mongolia University, Huhhot, 010021,, P.R. China |
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| Abstract: | The cyanohydrin trimethylsilyl ether of o-chlorobenzoylferrocene has been synthesized by the addition of trimethylsilyl cyanide (TMSCN) in methylene chloride in the presence of zinc iodide. Its structure was determined by X-ray single crystal diffraction. The crystal belongs to monoclinic, space group P21/n with the following crystallographic parameters: a = 9.480(3) ?, b = 22.319(6) ?, c = 9.783(3) ?, β = 101.197(4)°, μ = 0.943 mm − 1, V=2030.5(10) ?3, Z=4, F(0 0 0) = 880, D
calc=1.386 mg/m3, T=293(2) K, 1.82° ≤ θ ≤ 26.40°, the final R factor: R
1=0.0366, wR
2=0.0802. |
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| Keywords: | Ferrocene compound Cyanohydrin trimethylsilyl ether of
o-chlorobenzoylferrocene Crystal structure |
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