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A Personal Account on Inorganic Reaction Mechanisms |
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| Authors: | Justyna Polaczek Konrad Kieca Maria Oszajca Olga Impert Anna Katafias Debabrata Chatterjee Dušan Ćoćić Ralph Puchta Grażyna Stochel Colin D. Hubbard Rudi van Eldik |
| Affiliation: | 1. Faculty of Chemistry, Jagiellonian University, Gronostajowa 2, 30-387 Kraków, Poland Contribution: Conceptualization (lead), Writing - review & editing (lead);2. Faculty of Chemistry, Jagiellonian University, Gronostajowa 2, 30-387 Kraków, Poland Jagiellonian University, Doctoral School of Exact and Natural Sciences, Kraków, 30-348 Krakow, Poland Contribution: Conceptualization (equal), Writing - review & editing (equal);3. Faculty of Chemistry, Jagiellonian University, Gronostajowa 2, 30-387 Kraków, Poland;4. Faculty of Chemistry, Nicolaus Copernicus University in Torun, Gagarina 7, 87-100 Torun, Poland;5. Faculty of Chemistry, Nicolaus Copernicus University in Torun, Gagarina 7, 87-100 Torun, Poland Contribution: Conceptualization (lead), Writing - review & editing (lead);6. Faculty of Chemistry, Nicolaus Copernicus University in Torun, Gagarina 7, 87-100 Torun, Poland Vice-Chancellor's Research Group, Zoology Department, University of Burdwan, Burdwan, 713104 India Contribution: Conceptualization (lead), Writing - review & editing (lead);7. University of Kragujevac, Faculty of Science, Department of Chemistry, Radoja Domanovića 12, P. O. Box 60, 34000 Kragujevac, Serbia Contribution: Conceptualization (equal), Writing - review & editing (equal);8. Department of Chemistry and Pharmacy, University of Erlangen-Nuremberg, Egerlandstrasse 1, 91058 Erlangen, Germany Central Institute for Scientific Computing (CISC), University of Erlangen-Nuremberg, Martensstr. 5a, 91058 Erlangen, Germany Computer Chemistry Center, Department of Chemistry and Pharmacy, University of Erlangen-Nuremberg, Nägelsbachstr. 25, 91052 Erlangen, Germany Contribution: Conceptualization (lead), Writing - review & editing (lead);9. Department of Chemistry, University of New Hampshire, Durham, 03824 USA Contribution: Conceptualization (equal), Writing - review & editing (equal);10. Department of Chemistry and Pharmacy, University of Erlangen-Nuremberg, Egerlandstrasse 1, 91058 Erlangen, Germany |
| Abstract: | The presented Review is focused on the latest research in the field of inorganic chemistry performed by the van Eldik group and his collaborators. The first part of the manuscript concentrates on the interaction of nitric oxide and its derivatives with biologically important compounds. We summarized mechanistic information on the interaction between model porphyrin systems (microperoxidase) and NO as well as the recent studies on the formation of nitrosylcobalamin (CblNO). The following sections cover the characterization of the Ru(II)/Ru(III) mixed-valence ion-pair complexes, including Ru(II)/Ru(III)(edta) complexes. The last part concerns the latest mechanistic information on the DFT techniques applications. Each section presents the most important results with the mechanistic interpretations. |
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