Reactions of 1-bromo-1-nitro-3,3,3-trichloropropene with O- and N-nucleophiles |
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| Authors: | E. V. Stukan’ S. V. Makarenko G. A. Berkova V. M. Berestovitskaya |
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| Affiliation: | 1.Herzen Russian State Pedagogical University,St. Petersburg,Russia |
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| Abstract: | Reactions of 1-bromo-1-nitro-3,3,3-trichloropropene with alcohols, benzidine and o-, m-, and p-phenylenediamines was investigated and the reaction conditions were developed. The alkoxylation and amination products and an unusual nitrogen-containing bis-aziridine were obtained; their structures were characterized by the spectral (IR, 1H, 13C NMR, HMQC, and HMBC) methods. |
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