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对氯偶氮氯膦光度法连续测定矿石中稀土总量与钪
引用本文:陈婉如,陈嘉丽,潘教麦. 对氯偶氮氯膦光度法连续测定矿石中稀土总量与钪[J]. 分析测试学报, 1991, 0(3)
作者姓名:陈婉如  陈嘉丽  潘教麦
作者单位:华东师范大学化学系 上海(陈婉如,陈嘉丽),华东师范大学化学系 上海(潘教麦)
摘    要:在一定的条件下,对氯偶氮氯膦(CPA_pC)与等量的15种单一稀土所形成的络合物具有彼此相似的吸光度值。且该试剂也是钪的灵敏显色剂。据此分析特性,连续测定了矿石中稀土总量与钪,分析结果与标准数据基本相符。

关 键 词:对氯偶氮氯膦  稀土  钪的测定  光度分析

Successive Spectrophotometric Determination of Total Rare Earths and Scandium in Ores with Chlorophosphonazo-p-CL
Chen Wanru,Chen Jiali,Pan Jiaomai. Successive Spectrophotometric Determination of Total Rare Earths and Scandium in Ores with Chlorophosphonazo-p-CL[J]. Journal of Instrumental Analysis, 1991, 0(3)
Authors:Chen Wanru  Chen Jiali  Pan Jiaomai
Affiliation:Chen Wanru,Chen Jiali,Pan Jiaomai Department of Chemistry,East China Normal University,Shanghai
Abstract:Under the certain experimental conditions, the complexes formed in the reactions of CPApCwith 15 rare earths have approximate absorbance values. Additionally, CPApC is also a sensitivechromogenic reagent of scandium. Based on these analytical characteristics, a new method for thesuccessive determination of total rare earths and scandium with CPApC was developed. This me-thod has been applied to the ores analysis. The results are coincident with the standard data.
Keywords:CPA_pC  detemination of rare earths and scandium  spectrophotometry
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