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Calmagite as a spectrophotometric reagent for aluminium
Authors:Woodward C  Freiser H
Institution:Department of Chemistry, University of Arizona, Tucson, Arizona 85721, U.S.A.
Abstract:Calmagite is proposed as a sensitive spectrophotometric reagent for aluminium, (570mmu) = 42000. After aqueous phase reaction at pH 8.6, the metal-reagent complex is extracted into chloroform by formation of an ion-association complex with a quaternary ammonium salt. The method is free from interference by common anions, and cationic interferences may be eliminated by the use of cyanide and EDTA as masking agents.
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