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Complexometric titration of calcium in the presence of larger amounts of magnesium
Authors:Tsunogai S  Nishimura M  Nakaya S
Institution:Department of Chemistry, Faculty of Fisheries, Hokkaido University, Hakodate, Japan.
Abstract:A simple and accurate titrimetric determination of calcium in the presence of larger amounts of magnesium is proposed. Calcium is extracted into a small volume of organic solvent as its glyoxal-bis(2-hydroxyanil) complex, and the calcium is titrated with EGTA. The end-point is sharp, and occurs when the red colour of the organic layer vanishes. This method has been successfully applied to the determination of calcium in sea-water with an error less than 0.1%.
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