Aqueous hydrogenation of carbon dioxide catalysed by water-soluble ruthenium aqua complexes under acidic conditions |
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| Authors: | Hayashi Hideki Ogo Seiji Fukuzumi Shunichi |
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| Affiliation: | Department of Material and Life Science, Graduate School of Engineering, Osaka University, PRESTO & CREST, Japan Science and Technology Agency (JST), Suita 565-0871, Japan. |
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| Abstract: | Hydrogenation of carbon dioxide (P(H2/CO2)= 5.5/2.5 MPa) into formic acid (HCOOH) under acidic conditions (pH 2.5-5.0) in water has been achieved by using water-soluble ruthenium aqua catalysts [(eta6-C6Me6)RuII(L)(OH2)]SO4 (L = 2,2'-bipyridine or 4,4'-dimethoxy-2,2' bipyridine). |
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