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Upconversion-powered photoelectrochemistry
Authors:Khnayzer Rony S  Blumhoff Jörg  Harrington Jordan A  Haefele Alexandre  Deng Fan  Castellano Felix N
Institution:Department of Chemistry and Center for Photochemical Sciences, Bowling Green State University, Bowling Green, Ohio 43403, USA.
Abstract:Upconversion photochemistry occurring between palladium(II) octaethylporphyrin (PdOEP, 1) and 9,10-diphenylanthracene (DPA, 2) in toluene successfully sensitizes nanostructured WO(3) photoanodes (E(g) = 2.7 eV) to sub-bandgap non-coherent green photons at low power density.
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