| 富勒烯硫化反应进展 |
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| 引用本文： | 吴胜莉,李宗军,高翔.富勒烯硫化反应进展[J].应用化学,2019,36(4):392-401. |
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| 作者姓名： | 吴胜莉 李宗军 高翔 |
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| 作者单位： | 中国科学院长春应用化学研究所,电分析化学国家重点实验室 长春 130022;中国科学院大学 北京 100049 |
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| 基金项目： | 国家自然科学基金(21472183)、吉林省科技发展计划项目 (20170101172JC,20160520128JH)资助 |
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| 摘 要： | 富勒烯官能化研究是富勒烯化学的重要组成部分。 近年来,随着富勒烯化学研究的深入发展,许多新颖富勒烯衍生物被陆续合成出来,并在生物医学和有机太阳能电池方面显示出良好的应用潜力。 与快速发展的富勒烯化学相比,富勒烯硫化反应研究进展较慢,近年来逐步引起广泛兴趣。 在此,我们结合本课题组开展的工作,对富勒烯硫化反应的最新进展进行总结。
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| 关 键 词： | 富勒烯 硫化反应 富勒烯硫化物 反应机理 |
| 收稿时间： | 2018-11-16 |
Progress on Thiolation Reactions of Fullerenes |
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| WU Shengli,LI Zongjun,GAO Xiang.Progress on Thiolation Reactions of Fullerenes[J].Chinese Journal of Applied Chemistry,2019,36(4):392-401. |
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| Authors: | WU Shengli LI Zongjun GAO Xiang |
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| Institution: | State Key Laboratory of Electroanalytical Chemistry,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China;University of Chinese Academy of Sciences,Beijing 100049,China |
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| Abstract: | Functionalization of fullerenes is an important part of fullerene chemistry. Many novel fullerene derivatives have been synthesized during recent years, and the compounds have exhibited promising potentials in biomedical chemistry and organic solar cells. Compared with the rapid development of fullerene chemistry, progress on the fullerene thiolation is slow, which has attracted more attention recently. Herein, the latest progress on the thiolation reactions of fullerenes is reviewed, which includes the recent result from our group. |
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| Keywords: | fullerenes thiolation reactions thiolated fullerene derivatives reaction mechanism |
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