| 铁催化的交叉偶联反应研究进展 |
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| 引用本文： | 周文俊,邓家英.铁催化的交叉偶联反应研究进展[J].应用化学,2016,33(3):245-266. |
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| 作者姓名： | 周文俊 邓家英 |
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| 作者单位： | 内江师范学院化学化工学院;果类废弃物资源化四川省高等学校重点实验室 四川 内江 641112 |
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| 基金项目： | 四川省教育厅培育项目(12ZZ012);青年基金项目(11ZB024,12ZB074,13ZB0002);内江师范学院博士科研启动经费资助项目 |
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| 摘 要： | 过渡金属催化的交叉偶联反应具有反应条件温和、操作简单、底物范围广等特点而备受关注,其中,铁在地球上存储丰富、廉价、无毒、对环境友好,商品化的铁盐和含铁化合物种类繁多,是一种可供选择的、绿色的、较为理想的催化剂。 近年来铁作为催化剂应用于交叉偶联反应的相关报道逐渐增多,本文根据铁催化剂的不同种类,综述了近年来铁盐催化交叉偶联反应的研究进展,期望为相关的研究工作提供参考。
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| 关 键 词： | 铁催化剂 交叉偶联反应 有机合成 进展 |
| 收稿时间： | 2015-06-15 |
Research Progress of Iron-catalyzed Cross-coupling Reactions |
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| ZHOU Wenjun,DENG Jiaying.Research Progress of Iron-catalyzed Cross-coupling Reactions[J].Chinese Journal of Applied Chemistry,2016,33(3):245-266. |
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| Authors: | ZHOU Wenjun DENG Jiaying |
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| Institution: | College of Chemistry and Chemical Engineering;Key Laboratory of Fruit Waste Treatment and Resource Recycling of the Sichuan Provincial College,Neijiang Normal University,Neijiang,Sichuan 641112,China |
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| Abstract: | Transition metal-catalyzed cross-coupling reaction which has advantages of simple operation, mild reaction conditions, and broad scope of substrates is one of the most efficient methods for the construction of carbon-carbon bonds. Iron is one of the potential green catalysts as it is one of the most abundant, inexpensive metals on earth, and environmentally friendly. Iron salts and iron-containing compounds are widely commercially available. Recently, more and more studies report the use of iron as catalyst in cross-coupling reactions. This paper reviews the recent advances in iron-catalyzed cross-coupling reactions based on different raw materials and we hope to provide some inspiration for relative research. |
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| Keywords: | iron catalysts cross-coupling reaction organic synthesis progress |
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