2.1 Anorganische industrielle Produkte |
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Authors: | Faramarz Wahdat und Rolf Neeb |
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Affiliation: | (1) Institut für Anorganische Chemie und Analytische Chemie, Johannes Gutenberg-Universität Mainz, Postfach 3980, D-6500 Mainz, Bundesrepublik Deutschland |
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Abstract: | Summary Digestion-free determination of trace-metals (Zn, Cd, Pb, Cu) in beverages by inverse voltammetry in a flow-through cell equipped with a mercury film-electrode is described. Optimal enrichment potentials are obtained by inspection of the pseudopolarograms of the elements in the original diluted sample solution. After the deposition step in the untreated sample solution stripping is effected in a proper supporting electrolyte after medium exchange. Values obtained by this techniques with various samples compare well with those obtained by usual procedures including wet digestion of the samples. |
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