Di and monocarbonyl complexes of rhodium(I) containing singly charged bidentate ligands |
| |
Authors: | Kalyani Goswami Mono M. Singh |
| |
Affiliation: | (1) Department of Chemistry, Dibrugarh University, 786004 Dibrugarh, Assam, India |
| |
Abstract: | Summary A series of neutral square planar rhodium(I) dicarbonyls containing singly charged bidentate ligands (salicylaldoxime, -benzoinoxime, -furildioxime, -benzildioxime, dimethylglyoxime, cupferron) has been prepared from three sources: (i) tetracarbonyl--dichlorodirhodium(I), (ii) solutions of hydrated rhodium chloride in DMF held under reflux and (iii) a carbonylated solution of hydrated rhodium chloride in boiling absolute alcohol. These dicarbonyls react with triphenylphosphine,-arsine and -stibine to yield monocarbonyl derivatives. The monocarbonyls form 1 : 1 adducts with TCNE. All complexes have been characterized by elemental analysis, i.r. and uv-visible spectra. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|