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TiO2 nanotubes: A novel solid phase extraction adsorbent for the sensitive determination of nickel in environmental water samples
引用本文:Xin Ning Zhao,Qi Zeng Shi,Guo Hong Xie,Qing Xiang Zhou. TiO2 nanotubes: A novel solid phase extraction adsorbent for the sensitive determination of nickel in environmental water samples[J]. 中国化学快报, 2008, 19(7): 865-867. DOI: 10.1016/j.cclet.2008.05.004
作者姓名:Xin Ning Zhao  Qi Zeng Shi  Guo Hong Xie  Qing Xiang Zhou
作者单位:a School of Chemistry and Environmental Sciences, Henan Normal University, Henan Key Laboratory for Environmental pollution Control, Key Laboratory for Yellow River and Huaihe River Water Environment and Pollution Control, Ministry of Education, Xinxiang 453007, China;b College of Resources and Environment, Henan Institute of Science and Technology, Xinxiang 453003, China
基金项目:Creative Talented Person's Fund of Henan Province,河南省自然科学基金,河南师范大学基金,Henan Key Laboratory for environmental pollution control
摘    要:A novel method was developed for the sensitive determination of nickel in environmental water samples by using TiO2 nanotubes, a new nanomaterial, as solid phase extraction absorbent. In general, TiO2 nanomaterials were often used for catalytic degradation of pollutants in environmental field, and only a very few application in environmental analytic chemistry. In present work, TiO2 nanotubes was firstly used for the enrichment of nickel and the factors would influence the preconcentration performance were optimized. Under the optimal conditions, TiO2 nanotubes exhibited its good enrichment capacity for nickel and the detection limit of the proposed method was 1 ng· mL^-1. The proposed method was validated with real water samples, and excellent results were obtained with the spiked recoveries in the range of 94.4-99.2%, respectively.

关 键 词:二氧化钛纳米管    火焰原子吸收光谱法  环境水样

TiO2 nanotubes :A novel solid phase extraction adsorbent for the sensitive determination of nickel in environmental water samples
Xin Ning Zhao,Qi Zeng Shi,Guo Hong Xie,Qing Xiang Zhou. TiO2 nanotubes :A novel solid phase extraction adsorbent for the sensitive determination of nickel in environmental water samples[J]. Chinese Chemical Letters, 2008, 19(7): 865-867. DOI: 10.1016/j.cclet.2008.05.004
Authors:Xin Ning Zhao  Qi Zeng Shi  Guo Hong Xie  Qing Xiang Zhou
Affiliation:a School of Chemistry and Environmental Sciences, Henan Normal University, Henan Key Laboratory for Environmental pollution Control, Key Laboratory for Yellow River and Huaihe River Water Environment and Pollution Control, Ministry of Education, Xinxiang 453007, China;b College of Resources and Environment, Henan Institute of Science and Technology, Xinxiang 453003, China
Abstract:A novel method was developed for the sensitive determination of nickel in environmental water samples by using TiO2 nanotubes,a new nanomaterial,as solid phase extraction absorbent.In general,TiO2 nanomaterials were often used for catalytic degradation of pollutants in environmental field,and only a very few application in environmental analytic chemistry.In present work,TiO2 nanotubes was firstly used for the enrichment of nickel and the factors would influence the preconcentration performance were optimized.Under the optimal conditions,TiO2 nanotubes exhibited its good enrichment capacity for nickel and the detection limit of the proposed method was 1 ng mL-1.The proposed method was validated with real water samples,and excellent results were obtained with the spiked recoveries in the range of 94.4-99.2%,respectively.
Keywords:TiO2 nanotubes  Nickel  Flame atomic absorption spectrometry
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