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Centers of charge nonuniformity and reduction of copper oxide CuO during irradiation with nitrogen ions
Authors:N N Loshkareva  Yu P Sukhorukov  S V Naumov  B A Gizhevskii  G N Tatarinova  T A Belykh
Institution:(1) Institute of Metal Physics, Ural Branch, Russian Academy of Sciences, 620219 Ekaterinburg, Russia;(2) Ural State Technical University, 620002 Ekaterinburg, Russia
Abstract:Long-range reduction of CuO to Cu2O and Cu was observed by irradiating polycrystals and different planes of CuO single crystals ((110) and (020)) with 16-MeV nitrogen ions with fluence 1017 cm−2. The infrared absorption spectra show an increase in the number of hole CuO4]5− and electronic CuO4]7− centers. The highest density of electronic centers and reduction occur near the surfaces of the samples. Fiz. Tverd. Tela (St. Petersburg) 41, 1564–1567 (September 1999)
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