Centers of charge nonuniformity and reduction of copper oxide CuO during irradiation with nitrogen ions |
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Authors: | N N Loshkareva Yu P Sukhorukov S V Naumov B A Gizhevskii G N Tatarinova T A Belykh |
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Institution: | (1) Institute of Metal Physics, Ural Branch, Russian Academy of Sciences, 620219 Ekaterinburg, Russia;(2) Ural State Technical University, 620002 Ekaterinburg, Russia |
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Abstract: | Long-range reduction of CuO to Cu2O and Cu was observed by irradiating polycrystals and different planes of CuO single crystals ((110) and (020)) with 16-MeV
nitrogen ions with fluence 1017 cm−2. The infrared absorption spectra show an increase in the number of hole CuO4]5− and electronic CuO4]7− centers. The highest density of electronic centers and reduction occur near the surfaces of the samples.
Fiz. Tverd. Tela (St. Petersburg) 41, 1564–1567 (September 1999) |
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