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硫氰酸铵-结晶紫-H2O 体系浮选分离钴
引用本文:李全民,赵春霞,卫伟.硫氰酸铵-结晶紫-H2O 体系浮选分离钴[J].分析试验室,2001,20(3):37-39.
作者姓名:李全民  赵春霞  卫伟
作者单位:河南师范大学化学与环境科学学院
摘    要:研究了硫氰酸铵-结晶紫-H2O 体系浮选分离 Co(Ⅱ)与 Ni(Ⅱ)、Fe(Ⅲ)、Mn(Ⅱ)、Al(Ⅲ)、Cd(Ⅱ) 等常见离子的方法及条件。当 NaCl 用量为 1 g,硫氰酸铵(0.1 mol/L)和结晶紫(1×10-3 mol/L)溶液用量分别为 1.5 mL 和 2.5 mL,总体积为 10 mL 时,控制 pH 1.0~2.0,即可实现 Co(Ⅱ) 与上述离子的分离。

关 键 词:  硫氰酸铵  结晶紫  浮选分离    二元缔合物
文章编号:1000-0720(2001)03-0037-03

Floatation separation of cobalt with ammonium thiocyanate-crystal violet -aqua system
LI Quanmin,ZHAO Chun-xia,WEI Wei.Floatation separation of cobalt with ammonium thiocyanate-crystal violet -aqua system[J].Chinese Journal of Analysis Laboratory,2001,20(3):37-39.
Authors:LI Quanmin  ZHAO Chun-xia  WEI Wei
Abstract:The flotation separation behaviour of cobalt with NH4SCN-CV(crystal violet)-H2O system and the conditions for separation of cobalt from other metal ions were studied. In the aqueous solution, Co(Ⅱ) was precipitated by reaction with thiocyanate and crystal violet, and the precipitate could be separated from aqueous solution by filtering. Under the optional conditions, the completely separation of Co(Ⅱ) from Zn(Ⅱ), Fe(Ⅲ), Cd(Ⅱ), Ni(Ⅱ), Mn(Ⅱ), Al(Ⅲ) was realized by floatation at pH 1.0~2.0.
Keywords:Cobalt  Ammonium thiocyanate  Crystal violet  Flotation separation
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