Heterobimetallic complexes of cis-1,2-bis(diphenylphosphine)ethene containing tin and nickel,palladium or platinum |
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| Authors: | Evilázio F de Assis Carlos A L Filgueiras |
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| Institution: | (1) Departamento de Química, Universidade Federal do Rio Grande do Norte, 59072 Natal, RN, Brazil;(2) Departamento de Química, Universidade Federal de Minas Gerais, 31270 Belo Horizonte, MG, Brazil |
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| Abstract: | Summary New heterobimetallic complexes of nickel, palladium or platinum and the ligand cis-1,2-bis(diphenylphosphine)-ethene, dppen, and tin were prepared. The transition metal is bonded either directly or via chlorine bridges to the tin atom. The compounds were obtained from precursor complexes of the general formula M(dppen)Cl2] (M = Ni, Pd or Pt) by reaction with Ph3SnH or SnCl2. |
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