| 哌啶类化合物和有机过氧化物体系引发甲基丙烯酸甲酯聚合的研究 |
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| 引用本文： | 张景义,丘坤元,冯新德. 哌啶类化合物和有机过氧化物体系引发甲基丙烯酸甲酯聚合的研究[J]. 高等学校化学学报, 1985, 6(8): 741 |
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| 作者姓名： | 张景义 丘坤元 冯新德 |
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| 作者单位： | 1. 北京大学第一分校;2. 北京大学化学系 |
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| 摘 要： | 本文研究了四种哌啶类环状脂肪胺哌啶(P)、2,2,6,6-四甲基-4-哌啶醇(TMP)、N-乙基哌啶(NEP)、1,2,2,6,6-五甲基-4-哌啶醇(PMP)分别与有机过氧化物过氧化苯甲酰(BPO)、过氧化月桂酰(LPO)、叔丁基过氧化氢(TBH)、过氧化笨甲酸叔丁酯(TBPB)组成的引发体系对甲基丙烯酸甲酯(MMA)聚合的影响。测定了聚合反应的表观活化能和动力学方程。
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| 收稿时间： | 1984-01-04 |
Studies on Methyl Methacrylate Polymerization Initiated with Piperidine Derivatives and Organic Peroxide Systems |
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| Zhang Jingyi,Qiu Kunyuan,Feng Xinde. Studies on Methyl Methacrylate Polymerization Initiated with Piperidine Derivatives and Organic Peroxide Systems[J]. Chemical Research In Chinese Universities, 1985, 6(8): 741 |
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| Authors: | Zhang Jingyi Qiu Kunyuan Feng Xinde |
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| Affiliation: | 1. The First Branch of Peking University, Beijing;2. Department of Chemistry, Peking University, Beijing |
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| Abstract: | The polymerization of methyl methacrylate initiated with piperidine derivatives (piperidine, 2,-2, 6, 6-tetramethyl-4-hydroxyl piperidinc, N-cthyl piperidine, 1,2, 2, 6, 6-pentamethyl-4-hydroxyl piperidine) and organic peroxides (benzoyl peroxide, lauroyl peroxide, t-butyl hydroperoxidc, t-butyl peroxybcnzoatc) systems was studi-ed in this paper. The polymerization rate cquation and the activation energy of polymerization were determined respectively. |
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