Unusual demethylation of 1-dimethylamine-1-carba-closo-dodecarbonate(11) |
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| Authors: | Jaromír Plašek Tomáš Jelínek Bohumil Štíbr |
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| Affiliation: | Institute of Inorganic Chemistry Prague, Czechoslovak Academy of Sciences, 250 68 ?e? near Prague, Czechoslovakia |
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| Abstract: | 1-Dimethylamine-1-carba-closo-dodecaborane(1), 1-(CH3)2NH-1-CB11H11, can be smoothly demethylated with iodine in weakly alkaline solution to produce 1-methylamine-1-carba-closo-dodecarborane(11), 1-CH3NH2-1-CB11H11. The latter compound undergoes formylation with formaldehyde and iodine to give 1-hydroxymethylene-methylamine-1-carba-closo-dodecaborane(11). Further chemical transformations of both compounds are reported. |
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| Keywords: | Author to whom correspondence should be addressed. |
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