Mechanism of the Oxidation of Cyclohexane by Peroxynitrous Acid in Media with and without Oxygen |
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| Authors: | Tret'yakov V P Min'ko L A Rudakov E S Alekhina T A |
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| Institution: | (1) L. M. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, 70 R. Luxemburg Vul., 83114 Donets'k, Ukraine |
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| Abstract: | A study was carried out on the products and kinetics of the reaction of cyclohexane with peroxynitrous acid (HOONO) in a three-phase system containing an aqueous solution, cyclohexane, and a gaseous phase (O2 or He). In both the helium and oxygen atmosphere, cyclohexanol is formed with a constant initial rate, while cyclohexane is formed after a considerable induction period related to the release of O2 upon the decomposition of HOONO. |
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| Keywords: | peroxynitrous acid cyclohexane oxidation oxygen mechanisms |
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