Allene functionalization via bicyclic methylene aziridines |
| |
Authors: | Boralsky Luke A Marston Dagmara Grigg R David Hershberger John C Schomaker Jennifer M |
| |
Institution: | Department of Chemistry, University of Wisconsin-Madison, Madison, Wisconsin 53706, USA. |
| |
Abstract: | The oxidative functionalization of olefins is a common method for the formation of vicinal carbon-heteroatom bonds. However, oxidative methods to transform allenes into synthetic motifs containing three contiguous carbon-heteroatom bonds are much less developed. This paper describes the use of bicyclic methylene aziridines (MAs), prepared via intramolecular allene aziridination, as scaffolds for functionalization of all three allene carbons. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|