Palladium-catalyzed enantioselective ring opening of oxabicyclic alkenes with organozinc halides |
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| Authors: | Li Ming Yan Xiao-Xia Hong Wei Zhu Xia-Zhen Cao Bo-Xun Sun Jie Hou Xue-Long |
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| Affiliation: | State Key Laboratory of Organometallic Chemistry and Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, China. |
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| Abstract: | Palladium-catalyzed asymmetric ring opening of oxabenzonorbornadienes with readily available organozinc halides under mild conditions in the presence of (S)-Pr(i)-PHOX produces the corresponding 1,2-dihydronaphth-1-ols in good yield and high enantioselectivity. [reaction: see text] |
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