Highly active heterogeneous palladium nanoparticle catalysts for homogeneous electrophilic reactions in solution and the utilization of a continuous flow reactor |
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| Authors: | Huang Wenyu Liu Jack Hung-Chang Alayoglu Pinar Li Yimin Witham Cole A Tsung Chia-Kuang Toste F Dean Somorjai Gabor A |
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| Affiliation: | Department of Chemistry, University of California, Berkeley, California 94720, United States. |
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| Abstract: | A highly active heterogeneous Pd-nanoparticle catalyst for the intramolecular addition of phenols to alkynes was developed and employed in a continuous flow reaction system. Running the reaction in flow mode revealed reaction kinetics, such as the activation energy and catalyst deactivation, and provides many potential practical advantages. |
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