Sequential enolboration/hydroformylation/aldol addition: a new one-pot cascade reaction for the regio- and diastereoselective formation of carbocyclic quaternary centres from acyclic olefins |
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| Authors: | Keränen Mark D Eilbracht Peter |
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| Institution: | Fachbereich Chemie, Organische Chemie I, Universit?t Dortmund, Otto-Hahn-Str. 6, D-44227 Dortmund, Germany. |
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| Abstract: | Starting from unsaturated carbonyl compounds a mild new cascade reaction involving enolboration, rhodium-catalysed hydroformylation and intramolecular aldol addition in a regio- and diastereoselective fashion leads to cyclic compounds containing highly-functionalised quaternary carbon centres. |
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