A new Ru-catalyzed cascade reaction forming polycyclic cyclohexadienes from 1,6-diynes and alkenes |
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| Authors: | Varela Jesús A Rubín Silvia G Gonzalez-Rodríguez Carlos Castedo Luis Saa Carlos |
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| Institution: | Departamento de Química Organica y Unidad Asociada al CSIC, Facultad de Química, Universidad de Santiago de Compostela, 15782 Santiago de Compostela, Spain. |
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| Abstract: | Functionalized bicyclic 1,3-cyclohexadienes can be easily prepared by a new cascade reaction which involves the Ru-catalyzed addition of acyclic alkenes to 1,6-diynes to give (Z)-hexatrienes, followed by a pure thermal 6e-pi electrocyclization. |
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