|
|||||
|
|
Rate Study of Proton Catalyzed SmI2 Reduction of 2‐Heptanone and 1,2‐Epoxydecane |
|
| Authors: | Tzuen‐Yeuan Lin Ming‐Ren Fuh Yu‐Sheng Lin Chang‐Rong Wen Jia‐Yung Lin Chiao‐Ling Hu |
| Abstract: | Rate constants directly measured from the GC‐analyzed method for SmI2 reduction of 2‐heptanone and 1,2‐epoxydecane in the presence of various proton sources were obtained. Water exhibits much stronger catalytic effect than methanol and t‐butanol. Dependence of reaction rates on concentration of SmI2 and temperature were studied. |
| Keywords: | Samarium diiodide 2‐Heptanone 1,2‐Epoxydecane |