Calcium(II) meso‐2,3‐diphenylsuccinate heptahydrate |
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Authors: | Gregory Morin Maoyu Shang Bradley D Smith |
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Abstract: | The title compound, Ca(C16H12O4)(H2O)6]·H2O, adopts a conformation about the central C—C bond that places the two carboxylate groups in an anti orientation. The crystal consists of layers of two‐dimensional arrays of 2,3‐diphenylsuccinate dianions which are linked by bridging Ca2+ cations. The unit cell contains two Ca2+ cations in an unusual four‐membered Ca—O—Ca—O ring in which the bridging O atoms belong to water molecules rather than carboxylates, i.e. polydi‐μ‐aqua‐bispentaaquacalcium(II)]]‐μ‐(meso‐2,3‐diphenylsuccinato‐O:O′)] succinate dihydrate]. |
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