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[η5,σ‐3,3‐Di­methyl‐1‐(2,3,4,5‐tetra­methyl­cyclo­penta­dienyl)­but‐1‐en‐2‐amino](η5‐penta­methyl­cyclo­penta­dienyl)titanium
Authors:Dianne D Ellis  Anthony L Spek
Abstract:The titanocene complex Ti(C10H15)(C15H23N)] features a penta­methyl­cyclo­penta­dienyl ligand and a substituted cyclo­penta­dienyl ligand Me4C5R, where R is an amino functional group which is subsequently attached to the titanium metal centre. The structure has been determined to ascertain the conformational properties of the side chain with regard to extended conjugation between the π systems and the nature of the amino interaction with the metal centre.
Keywords:
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