An alkyl–palladium(II) complex with a bidentate phosphine ligand: [1,3‐bis(diphenylphosphino)propane‐P,P′]dimethylpalladium(II) toluene hemisolvate |
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| Authors: | Adnan S. Abu‐Surrah,Tony Debaerdemaeker,Wolfgang Huhn,Bernhard Rieger,Martti Klinga,Timo Repo,Markku Leskel |
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| Affiliation: | Adnan S. Abu‐Surrah,Tony Debaerdemaeker,Wolfgang Huhn,Bernhard Rieger,Martti Klinga,Timo Repo,Markku Leskelä |
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| Abstract: | In the title compound, [Pd(CH3)2(C27H26P2)]·0.5C7H8, the Pd atom is at the centre of an approximately square‐planar arrangement of two P atoms and two methyl groups. The P—Pd—P angle [93.19 (3)°] is significantly larger than that in the corresponding dichloride complex [Pd(dppp)Cl2]. The toluene molecule is disordered across an inversion centre. |
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