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trans‐Chloro(2‐nitrobenzenethiolato‐S)bis(triphenylphosphine‐P)palladium(II) monoacetone solvate |
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| Authors: | John H Aupers George Ferguson Christopher Glidewell John N Low James L Wardell |
| Abstract: | Molecules of the title compound, PdCl(C6H4NO2S)(PPh3)2]·C3H6O, exhibit a slight distortion from exact planarity at the Pd atom towards tetrahedral, with P—Pd—P and Cl—Pd—S angles of 174.98 (3) and 174.19 (3)°, respectively. The Pd—Cl and Pd—S bonds are, respectively, long 2.3550 (11) Å] and short 2.3020 (12) Å] for their types; the S—C bond is also very short 1.744 (4) Å]. The solvating acetone molecule is linked to one of the phosphine ligands by means of a C—H?O hydrogen bond. |
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