Diiodobis(1‐methyl‐1,3‐imidazolium‐2‐thiolato‐S)mercury(II) |
| |
| Authors: | Gordana Pavlovi&#x; Zora Popovi&#x;
eljka Soldin Dubravka Matkovi&#x;‐alogovi&#x; |
| |
| Institution: | Gordana Pavlović,Zora Popović,Željka Soldin,Dubravka Matković‐Čalogović |
| |
| Abstract: | The reaction of 1‐methyl‐1,3‐imidazole‐2‐thione (meimtH) with mercury(II) iodide in methanol in a 2:1 molar ratio resulted in the formation of single crystals of the title compound, HgI2(C4H6N2S)2]. The Hg atom is coordinated by two I 2.7809 (9) and 2.7999 (8) Å] and two thione S atoms 2.520 (3) and 2.576 (3) Å] with irregular tetrahedral coordination geometry. The NH groups of the imidazole ring take part in intra‐ and intermolecular hydrogen bonds with I atoms N?I 3.596 (8) and 3.611 (9) Å, respectively] joining molecules into infinite chains parallel to the z axis. |
| |
| Keywords: | |
|
|
