Abstract: | The Sn atom in catena‐polytriphenyltin(IV)‐μ‐(3‐ureidopropionato‐O1:O3)], Sn(C6H5)3(C4H7N2O3)]n, is five‐coordinate and has a trans‐C3SnO2 trigonal‐bipyrmidal geometry arising from bridging through the O atom of the ureido fragment of an adjacent carboxylate group. Infinite chains propagate helically along the c axis and adjacent chains are linked by N—H?O N?O 2.851 (4) Å] hydrogen bonds into layers. |