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cis‐Di­chloro(5,8‐dioxa‐2,11‐dithia[12]‐o‐cyclo­phane)­palladium(II)
Authors:Il Yoon  Byeong Soon Yoo  Shim Sung Lee  Bong Gon Kim
Abstract:The preparation and crystal structure of the title compound, cis‐di­chloro­[6,9‐dioxa‐3,12‐di­thia­bi­cyclo­[12.4.0]­octadeca‐14,‐16,­18(1)‐tri­ene‐S,S′]­palladium(II), [PdCl2(C14H20O2S2)], are described. The Pd atom has a square‐planar environment, coordinated to two S atoms of the di­thia­dioxa macrocycle and to two Cl? ions. The non‐coordinating O atoms are oriented away from the metal coordination plane. Upon complexation, a bicyclic chelate structure, which consists of a seven‐ and an eleven‐membered ring, is formed.
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