cis‐Dichloro(5,8‐dioxa‐2,11‐dithia[12]‐o‐cyclophane)palladium(II) |
| |
Authors: | Il Yoon Byeong Soon Yoo Shim Sung Lee Bong Gon Kim |
| |
Abstract: | The preparation and crystal structure of the title compound, cis‐dichloro[6,9‐dioxa‐3,12‐dithiabicyclo[12.4.0]octadeca‐14,‐16,18(1)‐triene‐S,S′]palladium(II), [PdCl2(C14H20O2S2)], are described. The Pd atom has a square‐planar environment, coordinated to two S atoms of the dithiadioxa macrocycle and to two Cl? ions. The non‐coordinating O atoms are oriented away from the metal coordination plane. Upon complexation, a bicyclic chelate structure, which consists of a seven‐ and an eleven‐membered ring, is formed. |
| |
Keywords: | |
|
|