A host–guest complex of diaquabis[1‐hydroxy‐2(1H)‐pyridinethionato‐O,S]magnesium(II) and 2,2′‐dithiobis(pyridine N‐oxide) |
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Authors: | Andrew Bond William Jones |
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Abstract: | The title compound, Mg(C5H4NOS)2(H2O)2]·C10H8N2O2S2, is a two‐component host–guest material. The 2,2′‐dithiobis(pyridine N‐oxide) molecule has crystallographic twofold symmetry. The metal complex lies on an inversion centre and associates via C—H?S interactions into chains which thread the 2,2′‐dithiobis(pyridine N‐oxide) lattice in perpendicular directions. Hydrogen bonds exist between the water molecules of the diaquamagnesium units and the N—O groups of the host lattice. |
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