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A T‐shaped selenenyl halide
Authors:Zulfiqar Majeed  William R. McWhinnie  Philip R. Lowe
Abstract:The title selenenyl halide complex, 3‐iodo‐2‐phenyl‐3H‐3‐selenaindazole, C12H9IN2Se, has an almost planar conformation and a nearly ideal T‐shape for the Se(INC) moiety [Se—I 2.8122 (12), Se—C 1.881 (7) and Se—N2 2.051 (6) Å; C—Se—N 79.6 (3), C—Se—I 96.8 (2) and N—Se—I 176.17 (17)°]. This arrangement, together with the two selenium lone pairs, leads to a distorted trigonal‐bipyrimidal geometry about the Se atom. Intermolecular interactions are largely limited to stacking forces.
Keywords:
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