7‐{Diphenyl[(triphenylphosphine)aurio]phosphine(1+)‐P}‐8‐methyl‐7,8‐dicarba‐nido‐undecaborate(1–) dichloromethane hemisolvate |
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Authors: | Olga Crespo,M. Concepci n Gimeno,Peter G. Jones,Antonio Laguna |
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Affiliation: | Olga Crespo,M. Concepción Gimeno,Peter G. Jones,Antonio Laguna |
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Abstract: | The title compound, 7‐[(Ph2P)Au(PPh3)]‐8‐(CH3)‐7,8‐nido‐C2B9H10]·0.5CH2Cl2 or [Au(C15H23B9P)(C18H15P)]·0.5CH2Cl2, is the first reported gold derivative of the ligand [7‐(Ph2P)‐8‐(CH3)‐7,8‐nido‐C2B9H10]?. It has a mononuclear structure with the gold centre in an essentially linear coordination [P—Au—P 174.041 (15)°]. The open C2B3 face contains one H atom that is strongly bonded to the central B atom and semi‐bridging to a neighbouring B atom [B—H distances 1.070 (16) and 1.45 (3) Å]. |
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