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7‐{Di­phenyl­[(tri­phenyl­phos­phine)­aurio]­phos­phine(1+)‐P}‐8‐methyl‐7,8‐dicarba‐nido‐undecaborate(1–) dichloro­methane hemi­solvate
Authors:Olga Crespo  M Concepcin Gimeno  Peter G Jones  Antonio Laguna
Institution:Olga Crespo,M. Concepción Gimeno,Peter G. Jones,Antonio Laguna
Abstract:The title compound, 7‐(Ph2P)Au(PPh3)]‐8‐(CH3)‐7,8‐nido‐C2B9H10]·­0.5CH2Cl2 or Au(C15H23B9P)­(C18H15P)]·­0.5CH2Cl2, is the first reported gold derivative of the ligand 7‐­(Ph2P)‐8‐(CH3)‐7,8‐nido‐C2B9H10]?. It has a mono­nuclear structure with the gold centre in an essentially linear coordination P—Au—P 174.041 (15)°]. The open C2B3 face contains one H atom that is strongly bonded to the central B atom and semi‐bridging to a neighbouring B atom B—H distances 1.070 (16) and 1.45 (3) Å].
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