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Carbonyl­[di­hydro­bis­(pyrazol‐1‐yl‐κN2)­borato]­hydrido­bis­(tri‐p‐tolyl­phosphine‐κP)­ruthenium(II)
Authors:Seong Huh  Young Jun Park  Alan J Lough  Moo‐Jin Jun
Abstract:The title compound, RuH(C6H8BN4)(C21H21P)2(CO)], possesses two trans‐disposed tri‐p‐tolyl­phosphines in axial positions and the remaining ligands in equatorial positions. The overall geometry of the RuII ion is a distorted octahedral structure. The P—Ru—P axis deviates from linearity by about 13°. This distortion arises mainly from the steric congestion between the bulky phosphine moieties and the tetrahedral di­hydro­bis­(pyrazol‐1‐yl)­borate ligands.
Keywords:
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