(μ‐C‐meso‐5,5,7,12,12,14‐Hexamethyl‐1,4,8,11‐tetraazacyclotetradecane‐N‐acetato‐1κ5N,N′,N′′,N′′′,O:2κO′)tetrachloro‐1κCl,2κ3Cl‐cobalt(III)zinc(II) |
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Authors: | Kaliyamoorthy Panneerselvam Tian‐Huey Lu Ta‐Yung Chi Shu‐Fang Tung Chung‐Sun Chung |
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Abstract: | The crystal structure of the title compound, [CoCl(C18H37N4O2){ZnCl3}], has been determined by X‐ray diffraction.C‐meso‐5,5,7,12,12,14‐Hexamethyl‐1,4,8,11‐tetraazacyclotetradecane‐N‐acetate acts as a bridging ligand to coodinate with CoIII and ZnII ions. The CoIII ion is six‐coordinate in a nearly octahedral environment provided by one Cl atom, four N atoms of the bridging ligand, and one O atom. The ZnII ion is four‐coordinate in a distorted tetrahedral environment completed by three Cl atoms and an O atom of the bridging ligand. |
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