| 钯催化异腈参与的反应研究进展 |
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| 引用本文： | 习志威,刘立秋,王迎春. 钯催化异腈参与的反应研究进展[J]. 化学通报, 2021, 84(5): 450-459 |
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| 作者姓名： | 习志威 刘立秋 王迎春 |
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| 作者单位： | 吉首大学化学化工学院武陵山地区民族药解析与创制湖南省工程实验室 吉首416000 |
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| 基金项目： | 国家自然科学基金项目(21762017)、湖南省自然科学基金项目(2020JJ4499)和湖南省教育厅自然科学基金项目(20A413)资助 |
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| 摘 要： | 异腈常作为有机合成反应中一类重要的活泼合成子,可用于高效合成天然产物、药物分子以及具有潜在生物活性的含氮分子或杂环化合物.近几年,钯催化异腈参与的各类反应,特别是异腈插入反应已被广泛关注、研究以及应用,具有极其重要的实际意义.本文将根据不同反应类型介绍近几年有关钯催化异腈参与反应的最新研究进展.
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| 关 键 词： | 异腈 钯催化 插入反应 偶联反应 串联反应 |
| 收稿时间： | 2020-09-27 |
| 修稿时间： | 2020-12-04 |
Recent Advances in Palladium Catalyzed Isocyanide Reactions |
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| Xi Zhiwei,Liu Liqiu,Wang Yingchun. Recent Advances in Palladium Catalyzed Isocyanide Reactions[J]. Chemistry, 2021, 84(5): 450-459 |
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| Authors: | Xi Zhiwei Liu Liqiu Wang Yingchun |
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| Affiliation: | College of Chemistry and Chemical Engineering,Hunan Engineering Laboratory for Analyse and Drugs Development of Ethnomedicine in Wuling Mountains,Jishou University,Jishou,416000,College of Chemistry and Chemical Engineering,Hunan Engineering Laboratory for Analyse and Drugs Development of Ethnomedicine in Wuling Mountains,Jishou University,Jishou,416000,College of Chemistry and Chemical Engineering,Hunan Engineering Laboratory for Analyse and Drugs Development of Ethnomedicine in Wuling Mountains,Jishou University,Jishou,416000 |
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| Abstract: | As an important class of active synthons in organic synthesis, isocyanide is used to synthesize natural products, drug molecules and nitrogen-containing molecules or heterocyclic compounds with potential biological activity. In recent years, palladium-catalyzed various reactions involving isocyanide, especially the insertion reaction of isocyanide, have been widely concerned, studied and applied, which is of great practical significance. In this review, according to different reaction types, the latest research progress of palladium-catalyzed isocyanide reactions is introduced. |
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| Keywords: | Isocyanide, Pd-catalysis, Insertion reaction, Coupling reaction, Tandem reaction |
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