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μ‐(4,4′‐Bi­pyri­dine)‐N:N′‐bis[bis‐(pyrrol­idine­dithio­car­boxyl­ato‐S,S′)zinc(II)]
Authors:Xiao‐Feng Chen  Shu‐Hua Liu  Xu‐Hui Zhu  Jagadese J Vittal  Goek‐Kheng Tan  Xiao‐Zeng You
Abstract:The title compound, Zn2(C5H8NS2)4(C10H8N2)], consists of two bis(pyrrol­idine­dithio­carboxylato)­zinc molecules bridged by a 4,4′‐bi­pyridine molecule, and has a 222 symmetry. Each Zn atom forms a five‐coordinate pseudo‐square‐based pyramidal arrangement, with four Zn—S interactions and one Zn—N interaction; the Zn—N distance is 2.085 (3) Å and the Zn—S distances are in the range 2.3319 (8)–2.6290 (9) Å.
Keywords:
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