μ‐(4,4′‐Bipyridine)‐N:N′‐bis[bis‐(pyrrolidinedithiocarboxylato‐S,S′)zinc(II)] |
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Authors: | Xiao‐Feng Chen Shu‐Hua Liu Xu‐Hui Zhu Jagadese J Vittal Goek‐Kheng Tan Xiao‐Zeng You |
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Abstract: | The title compound, Zn2(C5H8NS2)4(C10H8N2)], consists of two bis(pyrrolidinedithiocarboxylato)zinc molecules bridged by a 4,4′‐bipyridine molecule, and has a 222 symmetry. Each Zn atom forms a five‐coordinate pseudo‐square‐based pyramidal arrangement, with four Zn—S interactions and one Zn—N interaction; the Zn—N distance is 2.085 (3) Å and the Zn—S distances are in the range 2.3319 (8)–2.6290 (9) Å. |
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