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[2‐(Isopropylthio)benzoato‐O,S]phenyl(triphenylphosphine)palladium(II) tetrahydrofuran solvate
Authors:Catharine Thompson  Gert J Kruger  Wolfgang H Meyer  Robert Brüll  Helgard G Raubenheimer
Abstract:In the title compound, Pd(C6H5)(C10H11O2S)(C18H15P)]·C4H8O, an iso­propyl­thio­benzoate ligand is coordinated in a bidentate fashion to the central Pd atom through the O and S atoms. The square‐planar geometry of the Pd atom is completed by a phenyl ligand and a tri­phenyl­phosphine group but is distorted by the bidentate ligand, which forms a six‐membered chelate ring. This ring deviates strongly from planarity, which is illustrated by the plane through the phenyl portion of the chelate ring forming a dihedral angle of 62.3 (1)° with the coordination plane.
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