Reaction of pyrroles with naphthoquinones. Synthesis of new pyrrolylnaphthoquinone dyes |
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Authors: | Claude Lion Richard Baudry Mir Hedayatullah Louis Da Conceio Michel Hocquaux Sylvie Genard Jean Maignan |
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Institution: | Claude Lion,Richard Baudry,Mir Hedayatullah,Louis Da Conceição,Michel Hocquaux,Sylvie Genard,Jean Maignan |
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Abstract: | The reaction of 1,4‐naphthoquinone (1) with N‐alkylpyrroles (2) gives a mixture of 2‐(pyrrol‐2‐yl)‐1,4‐naphthoquinones (3) and 2,5‐bis(1,4‐naphthoquinon‐2‐yl)pyrroles (4). The yields and the ratios of these two products depend greatly on the experimental conditions. The reaction has been extended to 5‐hydroxy‐1,4‐naphthoquinone (juglone, 5) and 1,2‐naphthoquinone (6). New pyrrolylnaphthoquinones are obtained. |
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