Diaquabis(4,5‐dihydro‐1,2,4‐triazolo[1,5‐a]pyrimidin‐5‐one‐N3)bis(thiocyanato‐N)nickel(II) |
| |
Authors: | Mohammad Abul‐Haj Miguel Quirs Juan M Salas |
| |
Institution: | Mohammad Abul‐Haj,Miguel Quirós,Juan M. Salas |
| |
Abstract: | The title compound, Ni(NCS)2(C5H4N4O)2(H2O)2], crystallizes in the triclinic space group P . The molecular unit contains two neutral molecules of 4,5‐dihydro‐1,2,4‐triazolo1,5‐a]pyrimidin‐5‐one (5HtpO) coordinated through the N atom in position 3, two thiocyanate ligands coordinated through their N atoms and two water molecules completing an octahedral environment around the NiII ion, which lies on a centre of inversion. The structure is stabilized by hydrogen bonding. Distances in the coordination sphere are Ni—N3(5HtpO) 2.132 (2), Ni—O(water) 2.085 (2) and Ni—N(thiocyanato) 2.040 (2) Å. |
| |
Keywords: | |
|
|