首页 | 本学科首页   官方微博 | 高级检索  
     检索      


trans‐(2‐Methyl­thio­benzoato‐O)phenylbis­(tri­phenyl­phosphine)­palladium(II), two conformational isomers
Authors:Gert J Kruger  Catharine Thompson  Wolfgang H Meyer  Robert Brüll  Helgard G Raubenheimer
Abstract:The title compound, trans‐Pd(C6H5)(C8H7O2S)(C18H15P)2], crystallizes in two modifications differing only in the orientation of the 2‐methyl­thio­benzoato ligand. In both cases, this ligand binds to the metal centre via one O atom in a monodentate fashion. The only significant difference is a rotation about the C(Ph)—COO bond, with O—C—C—C torsion angles having values of 6.3 (7) and 157.3 (3)° in the two isomeric forms.
Keywords:
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号