Abstract: | The title compound, trans‐Pd(C6H5)(C8H7O2S)(C18H15P)2], crystallizes in two modifications differing only in the orientation of the 2‐methylthiobenzoato ligand. In both cases, this ligand binds to the metal centre via one O atom in a monodentate fashion. The only significant difference is a rotation about the C(Ph)—COO bond, with O—C—C—C torsion angles having values of 6.3 (7) and 157.3 (3)° in the two isomeric forms. |