Heteroelectrocyclic reaction of 4‐azido‐3‐hydrazonoalkyl‐quinolines to 2‐arylaminopyrazolo[4,3‐c]quinolones |
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Authors: | Gerhard Hojas Werner Fiala Wolfgang Stadlbauer |
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Abstract: | 4‐Azido‐3‐acylquinolones 4 obtained from 4‐hydroxy derivatives 1 via tosylates 3 or chlorides 5, reacted with arylhydrazines 6 to generate 4‐azido‐3‐hydrazonoalkylquinolines 7. Thermolysis of 7 gave ring closure products which were assigned to 2‐arylaminopyrazolo4,3‐c]quinolones 10. The thermal decomposition conditions of the azides 4 and 7 were studied by differential scanning calorimetry (DSC). |
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