Transition metal complexes with pyrazole‐derived ligands. XI. [Zn(μ‐L)(HL)(OAc)]2 (HL is 4‐acetyl‐3‐amino‐5‐methylpyrazole) |
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| Authors: | Zoran D Tomi&#x;
eljko K Ja&#x;imovi&#x; Vukadin M Leovac Valeria I e&#x;ljevi&#x; |
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| Institution: | Zoran D. Tomi?,?eljko K. Ja?imovi?,Vukadin M. Leovac,Valeria I. ?e?ljevi? |
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| Abstract: | The title compound, bis(μ‐4‐acetyl‐3‐amino‐5‐methylpyrazolato‐N1:N2)bis(acetato‐O)(4‐acetyl‐3‐amino‐5‐methylpyrazole‐N2)zinc(II)], Zn2(C6H8N3O)2(C2H3O2)2(C6H9N3O)2], ex‐ists as a centrosymmetric binuclear molecule with two tetrahedrally coordinated Zn atoms bridged by two pyrazolate anions. The geometry of the terminal and bridging pyrazole ligands are slightly different as a consequence of their differing modes of coordination. |
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