Abstract: | In the title complex, MnHg(NCS)4(C3H8O2)]n, each Hg atom is tetrahedrally coordinated with four S atoms of the SCN? ions, and each Mn atom is octahedrally coordinated with four N atoms of the SCN? ions, one hydroxyl O atom and one ethereal O atom of the glycol monomethyl ether molecule. Each pair of Hg and Mn atoms is bridged by one SCN? ion. A 24‐membered Mn3Hg3(SCN)6 ring is formed as the strucrural unit, with the six metal atoms in a chair‐form hexagonal arrangement. The units are condensed and linked three‐dimensionally in the crystal resulting in a diamond‐like structure. |